Influence of different carrageenans on the particle size of dulce de leche for confectionery

Authors

DOI:

https://doi.org/10.33448/rsd-v11i5.27991

Keywords:

Particle size; Dulce de leche; Hydrocolloids.

Abstract

The objective of this work was to evaluate the influence of the addition of carrageenan on the particle size distribution of dulce de leche for confectionery. The experimental design adopted (n=3) was in a 2x3 factorial scheme, as follows: two types of carrageenan (Lactogel FX 6369 and Viscarin BK 7161) in three different concentrations (0.0% m/m, 0.3% m/m 0.5% w/w). Particle size analyzes of the products were performed by laser diffraction in order to identify the influence of the treatments. In the initial step of the process, which was the mixing of the ingredients, it was possible to observe the influence of the carrageenans on the particle size distribution with a reduction in the volumes (%) of the particle populations in the nanometric region of the casein micelles (between 0.04 µm and 0.4 µm) and fat globules (between 1.0 µm and 10 µm), providing the formation of particles in a third (20 µm) and a fourth region (above 40 µm). This displacement of particles to regions of greater diameter suggests the influence of carrageenans even before the heating and evaporation stage. A significant decrease in the volume (%) of particles smaller than 1.0 µm was also observed in products manufactured without the addition of carrageenan, on the same day of manufacture and also after 15, 30 and 45 days of shelf-life. This effect was not observed in products with the addition of carrageenan. These results demonstrate the influence of these thickeners/stabilizers on the maintenance of particles in the nanometric region of casein micelles, directly influencing the formation of the three-dimensional matrix of dulce de leche for confectionery and its technofunctional aspects.

References

Brasil (1997). Ministério da Agricultura, Pecuária e Abastecimento. Secretaria de Defesa Agropecuária. Departamento de Inspeção de Produtos de Origem Animal. Portaria n° 354, de 4 de setembro de 1997.

Campos, N. S. (2021). Identificação e caracterização de pontos brancos (PIPS) em doce de leite. Dissertação (Mestrado em Química). Universidade Federal de Juiz de Fora, Juiz de Fora.

Carneiro, L. C. M., Pinto, C. B. A., Gomes, E. R., de Paula, I. L., Wolfschoon Pombo, A. F., Stephani, R., Carvalho, A. F. & Perrone, I. T. (2021). The chemistry and technology of dulce de leche: a review. Research, Society and Development, 10, 11, e155101119408.

Costa, C. H. F. (2016). Avaliação microestrutural do leite pasteurizado submetido ao teste do álcool visando processamento UHT. Dissertação (Mestrado em Ciência e Tecnologia de Leite e Derivados). Universidade Federal de Juiz de Fora, Juiz de Fora.

Dalgleish, D. G. & Morris, E. R. (1988). Interactions between carrageenans and casein micelles: electrophoretic and hydrodynamic properties of particles. Food Hydrocolloids, 2, 311–320.

De Vries, J. (2002). Interaction of carrageenan with other ingredients in dairy dessert gels. In: Williams, P. A.; Phillips, G. O. (org.), Gums and stabilizers for the food industry, 11, 200-210, London: Royal Society of Chemistry.

Dodeja, A. K. et al. (1990). Heat transfer during evaporation of milk to high solids in thin film scraped surface heat exchanger. Journal of Food Process Engineering, 12, 211-225.

Gaze, L. V., Costa, M. P., Monteiro, M. L. G., Lavorato, J. A. A., Júnior, C. C., Raices, R. S. L. & Freitas, M. Q. (2015a). Dulce de Leche, a typical product of Latin America: Characterisation by physicochemical, optical and instrumental methods. Food Chemistry, 169, 471-477.

Gaze, L. V., Oliveira, B. R., Ferrao, L. L. Granato, D., Cavalcanti, R. N., Júnior, C. C. & Freitas, M. Q. (2015b). Preference mapping of dulce de leche commercialized in Brazilian markets. Journal of Dairy Science, 98, 1443-1454.

Ji, S., Corredig, M. & Goff, H. D. (2008). Aggregation of casein micelles and κ-carrageenan in reconstituted skim milk. Food Hydrocolloids, 22, 56-64.

Langendorff, V., Cuvelier, G., Michon, C., Launay, B., Parker, A. & De Kruif, C. G. (1999). Casein micelles/iota–carrageenan interactions in milk: Influence of temperature. Food Hydrocolloids, 13, 211-218.

Langendorff, V., Cuvelier, G., Michon, C., Launay, B., Parker, A. & De Kruif, C. G. (2000). Effects of carrageenan type on the behaviour of carrageenan/milk mixtures. Food Hydrocolloids, 14, 273-280.

Machado, L. M. P. (2005). Uso de soro de queijo e amido de milho modificado na qualidade do doce de leite pastoso. 170 p. Tese (Doutorado em Tecnologia de Alimentos). Universidade Estadual de Campinas, Campinas.

Necas, J. & Bartosikova, L. (2013). Carrageenan: a review. Veterinarni Medicina, 58, (4): 187-205.

Penna, A. L. B. (1998). Hidrocolóides – usos em Alimentos. Caderno de Tecnologia de Alimentos & Bebidas. Revista Food Ingredients, 58-64.

Perrone, I. T., Renhe, I. R. T., Pereira, J. P. F., Colombo, M., Coelho, J. S. & Magalhães, F. A. R. (2011). Influência de diferentes espessantes nas características sensoriais do doce de leite para confeitaria. Revista do Instituto de Laticínios Cândido Tostes, 379, 66, 45-50.

Perrone, I. T., Stephani, R., de Carvalho, A. F., Netto, G. G. & Francisquini, J. A. (2019). Doce de Leite: Química e Tecnologia. (2a ed.), CAP-LAB, 151 p.

Picullel, L. (1995). Gelling carrageenans. In: Stephen, A. M. (org.), Food polysaccharides and their applications, 205–243, Marcel Dekker.

Rees, D. A., Steele, I. W. & Williamson, F. B. (1969). Conformational analysis of polysaccharides. III. The relation between stereochemistry and properties of some polysaccharide sulfates. Journal of Polymer Science. Part C, 28, 261–276.

Schorsch, C., Jones, M. G. & Norton, I. T. (2000). Phase behavior of pure micellar casein/κ-carrageenan systems in milk salt ultrafiltrate. Food Hydrocolloids, 14, 347-358.

Silva, F. L., Ferreira, H. A. L., de Souza, A. B., de Freitas Almeida, D., Stephani, R., Pirozi, M. R. & Perrone, I. T. (2015). Production of dulce de leche: The effect of starch addition. LWT-Food Science and Technology, 62, 417-423.

Stephani, R., Francisquini. J., Perrone, I. T., de Carvalho, A. F. & de Oliveira, L. F. C. (2019). Dulce de leche – chemistry and processing technology. Milk production, processing and marketing, IntechOpen.

Teran-Ortiz, G. P. (1998). Efeito de adição de gomas xantana e locusta na cinética de inibição de cristalização de açúcares em doce de leite. Dissertação (Mestrado em Ciências dos Alimentos). Universidade Federal de Lavras, Lavras.

Walstra, P. et. al. (1999). Dairy Technology: principles of Milk properties and process. Food Science and Technology. Marcel Dekker, Inc. Basel.

Published

17/04/2022

How to Cite

DIAS, B. A. de C.; CAMPOS, N. da S.; ANJOS, J. P. S. dos .; CARVALHO, A. F. de .; PERRONE, Ítalo T.; OLIVEIRA, L. F. C. de .; STEPHANI, R. Influence of different carrageenans on the particle size of dulce de leche for confectionery. Research, Society and Development, [S. l.], v. 11, n. 5, p. e59911527991, 2022. DOI: 10.33448/rsd-v11i5.27991. Disponível em: https://www.rsdjournal.org/index.php/rsd/article/view/27991. Acesso em: 26 apr. 2024.

Issue

Section

Agrarian and Biological Sciences