Mezclas binarias de ZnO/TiO2 para la catálisis solar heterogénea de carbono orgánico no purgable en lixiviados de rellenos sanitarios

Autores/as

DOI:

https://doi.org/10.33448/rsd-v11i6.24570

Palabras clave:

Dióxido de titanio; Óxido de zinc; Fotocatálisis heterogénea.

Resumen

El lixiviado de los relleno sanitario es un problema global que ha atraído una atención considerable por parte de investigadores en diferentes campos. Es fundamental desarrollar estrategias de tratamiento optimizadas para estos lixiviados, dada la necesidad de minimizar o eliminar los impactos ambientales negativos resultantes de la disposición inadecuada de residuos sólidos, según lo determine la legislación. El lixiviado de relleno sanitario está compuesto principalmente por sustancias húmicas, que pueden estar asociadas con otras moléculas tóxicas y recalcitrantes a los tratamientos convencionales utilizados en Brasil. Este estudio estimó la degradación fotocatalítica de materiales carbonosos en un lixiviado recolectado en el relleno sanitario municipal de Cachoeira Paulista, São Paulo, Brasil. La luz solar se utilizó como fuente de energía, sin utilizar fuentes de energía adicionales. Los experimentos se llevaron a cabo en un reactor de reactor de lecho fijo de película fina, utilizando láminas de metal revestidas con pinturas especialmente formuladas. Las tintas tenían una carga aditiva baja, incluidos los fotocatalizadores. Investigamos el comportamiento fotocatalítico del sistema binario ZnO/TiO2 incorporado en barniz acrílico sobre la degradación del carbono orgánico no depurable (NOPC) en muestras de ácidos húmicos y ácidos fúlvicos + huminas. Las reacciones se realizaron en condiciones ácidas, neutras o alcalinas.La degradación de NOPC fue baja en muestras de ácido fúlvico + húmina, independientemente de la concentración de fotocatalizador o el pH. El proceso propuesto resultó en una alta degradación de ácidos húmicos, especialmente en condiciones de baja estabilidad química, lo que facilitó la oxidación. Se logró una degradación máxima del 65% de los ácidos húmicos utilizando altas concentraciones de TiO2 en un medio ácido.

Biografía del autor/a

Nicoly Milhardo Lourenço Nohara, University of São Paulo

Master in Science from the Postgraduate Program in Chemical Engineering at the Engineering of Lorena/USP (2018-2021). The subject of the dissertation heterogeneous photocatalysis of recalcitrant organic compounds contained in landfill leachate. During this period, she participated as an intern in the Teaching Initiation Program in the discipline of Materials Science and Engineering. She holds a Bachelor's Degree in Environmental and Sanitary Engineering from the University of Taubaté (2012-2016). During her graduation, she was a Scientific Initiation Scholar (a) in a project on bioaccumulation of metals in algae (PIC / UNITAU) and (b) in a project on materials absorbing electromagnetic radiation (PIBIC / CNPq). She also participated in an Extension Project on the elaboration of the Management Plan for the Municipal Park of Itaim (Taubaté-SP), in addition to doing a teaching internship in the subject of Calculus. The final graduation work involved a literature review on processes for obtaining biomethane for injection into the distribution network. Between 2010 and 2011, she took a Technical course in the Environment at ETEC in São Sebastião and developed an anaerobic biodigester for the production of biogas as a conclusion.

Helcio José Izário Filho, University of São Paulo

Graduated in Chemical Engineering from the Faculty of Chemical Engineering of Lorena (1985), Master's in Materials Engineering from the Faculty of Chemical Engineering of Lorena (1993) and Ph.D. in Chemistry from the State University of Campinas (1999). He is currently a professor at the School of Engineering of Lorena-EEL / USP, with PQ-2 Research Productivity. Has experience in Chemistry, with an emphasis on Analytical Instrumentation, specifically in atomic absorption and emission spectrometry and spectrophotometry, acting on the following topics: inorganic characterization and environment (analytical characterization of solid and liquid waste and Advanced Oxidative Processes).

Marco Aurélio Kondracki de Alcântara, University of São Paulo

Marco Aurélio Kondracki de Alcântara studied Agronomic Engineering at the Federal University of Rio Grande do Sul - UFRGS. Has a Masters in Soil Sciences also at UFRGS, a Doctorate in Agricultural Engineering at the State University of Campinas - FEAGRI-UNICAMP and Post-doctorate at the Center for Research and Development of Soils and Agro-environmental Resources of the Agronomic Institute of Campinas - IAC-CPDSRA. Areas of expertise: waste treatment by advanced oxidative processes and soil pollution. He also works in the area of soil pollution. Currently, is he a Professor at the School of Engineering of Lorena at the University of São Paulo? EEL-USP, where he teaches courses in Soil, Basic Ecology and Environmental Engineering. In School at Colégio Técnico de Lorena, he teaches Biology subjects. Is he currently a Member of the Environmental Engineering Course Committee - CoC-EA, as Substitute for the Course Coordination.

Gabriel Caracciolo Koenigkam de Oliveira, University of São Paulo

He is currently a Technician at the Laboratory of Spectrophotometry at the School of Engineering of Lorena - USP. He has a background in Chemistry.

Fernando Vernilli Junior, University of São Paulo

Post Doctorate from UFSCar, Doctor in Chemistry from UNESP, Master in Materials Engineering and Chemical Engineer from EEL-USP. Associate Professor, Vice Mayor of the USP Campus in Lorena and CNPq Productivity Scholarship in Technological Development and Innovation. He was President of the Graduate Committee at EEL-USP for 3 terms, and also Coordinator of the Graduate Program in Materials Engineering at EEL-USP for 2 terms. He has over 35 years of experience in the development and characterization of ceramic materials. Acting in the synthesis of raw materials by hydrometallurgy and development of new ceramic materials, mainly refractories for the metallurgical sector, conducting research on modern techniques in the reuse of waste generated in the steel industry.

Evandro Luís Nohara, University of Taubaté

Graduated in Technological Chemistry from Universidade Estadual Paulista Júlio de Mesquita Filho (1996), Master's from Instituto Tecnológico de Aeronáutica (1998) and Doctorate Sandwich from Instituto Tecnológico de Aeronáutica and Moscow Power Engineering Institute (2003). He has been a professor at the Department of Mechanical Engineering at the University of Taubaté since 2003, where he has been teaching for undergraduate and postgraduate courses in materials sciences, and in the execution of R&D projects in the area of Materials Engineering and Aerospace Engineering, working in the following areas. topics: processing and characterization of structural polymer composites, electromagnetic radiation absorbing materials and nanotechnology. He has been an Honorary Member of the Brazilian Air Force since 2008. He is the current Coordinator of the Professional Master's Program in Mechanical Engineering at the University of Taubaté.

Kleberson Aristogenio de Oliveira, University of Taubaté

Kleberson Aristogenio de Oliveira has basic training: Aeronautical Engineering from the University of Taubaté - UNITAU and Technician in Informatics from ETEC de Cruzeiro. His professional experience includes approximately six years as a Tool Adjuster at IOCHPE Maxion S/A, ten months as an intern at the Materials and Mechanical Testing Laboratory - UNITAU, and ten months as a Senior Monitor, in the disciplines: Technology of metallic aeronautical materials and Materials technology composite aeronautics, at the University of Taubaté. He is currently studying for a Master's Degree in Mechanical Engineering at the University of Taubaté.

Marcos Fernandes de Oliveira, Oswaldo Cruz Faculties

Ph.D. degree in Materials Engineering at Polytechnic School of the University of São Paulo, Brazil (2006). Graduated in Industrial Chemist in 1990 at Guarulhos University, São Paulo, Brazil. Specialist Chemist for DuPont do Brasil, during 29 years researching OEM coatings for car manufacturers (Toyota, Honda, Mitisubishi, Volvo, General Motors, Volkswagen and Ford). In 2002 and 2003, received the DuPont Safety Health Environment Prize for projects to reduce the volatile organic content in OEM coatings. In 2004, 2006, 2010 and 2017 received the 9th, 10th, 12th and 18th Science and Technology Coatings Award from Brazilian Paint Manufacturers Association (ABRAFATI) for works with organosilanes to reduce the corrosion rate in automotive carbon steel, carbon black pigments studies to avoid corrosion in steel tanks, magnesium oxide as ecological corrosion inhibitor, and nanoceramic as pretretament, respectively. Professor of Materials Science (Cure Mechanisms of Polymeric Films) for Coatings Technology Post graduation Course - Oswaldo Cruz College, São Paulo Brazil

Citas

ABRELPE - Associação Brasileira de Empresas de Limpeza Pública e Resíduos Especiais. (2020). Panorama dos resíduos sólidos no Brasil 2019/2020. Abrelpe. https://abrelpe.org.br/panorama-2020/

Azeez, F., Al-Hetlani, E., Arafa, M., Abdelmonem, Y., Nazeer, A. A., Amin, M. O., & Madkour, M. (2018). The effect of surface charge on photocatalytic degradation of methylene blue dye using chargeable titania nanoparticles. Scientific Reports, 8(1), 7104. https://doi.org/10.1038/s41598-018-25673-5

Brito, R. A., Filho, H. J. I., Aguiar, L. G., Alcântara, M. A. K., Siqueira, A. F., & Rós, P. C. M. D. (2019). Degradation Kinetics of Landfill Leachate by Continuous-Flow Catalytic Ozonation. Industrial & Engineering Chemistry Research, 58(23), 9855–9863. https://doi.org/10.1021/acs.iecr.9b01391

Chemlal, R., Azzouz, L., Kernani, R., Abdi, N., Lounici, H., Grib, H., Mameri, N., & Drouiche, N. (2014). Combination of advanced oxidation and biological processes for the landfill leachate treatment. Ecological Engineering, 73, 281–289. https://doi.org/10.1016/j.ecoleng.2014.09.043

Dia, O., Drogui, P., Buelna, G., Dubé, R., & Ihsen, B. S. (2017). Electrocoagulation of bio-filtrated landfill leachate: Fractionation of organic matter and influence of anode materials. Chemosphere, 168, 1136–1141. https://doi.org/10.1016/j.chemosphere.2016.10.092

Islam, Md. T., Dominguez, A., Turley, R. S., Kim, H., Sultana, K. A., Shuvo, M., Alvarado-Tenorio, B., Montes, M. O., Lin, Y., Gardea-Torresdey, J., & Noveron, J. C. (2020). Development of photocatalytic paint based on TiO2 and photopolymer resin for the degradation of organic pollutants in water. Science of The Total Environment, 704, 135406. https://doi.org/10.1016/j.scitotenv.2019.135406

Izário Filho, H. J., Siqueira, A. F., Alcântara, M. A. K., Aguiar, L. G., & Cavalcanti, A. S. (2018). Carbonaceous decomposition of a recalcitrant effluent treated by the photo-Fenton process: A kinetic approach. Environmental Technology, 41(4), 411–419. https://doi.org/10.1080/09593330.2018.1499813

Izário Filho, H. J., Siqueira, A. F., Alcântara, M. A. K., Aguiar, L. G., Rós, P. C. M. D., Napoleão, D. A. D. S., Cavalcanti, A. S., & Brandão, J. J. (2021). Solar photo-Fenton oxidation of mature landfill leachate: Empirical model and chemical inferences. Environmental Technology, 42, 1–8. https://doi.org/10.1080/09593330.2021.1909656

Jašková, V., Hochmannová, L., & Vytřasová, J. (2013). TiO2 and ZnO Nanoparticles in Photocatalytic and Hygienic Coatings. International Journal of Photoenergy, 2013, 1–6. https://doi.org/10.1155/2013/795060

Jones, F. N., Nichols, M. E., & Pappas, S. P. (2017). Organic coatings: Science and technology (Fourth edition). John Wiley & Sons, Inc.

Klučáková, M. (2018). Conductometric study of the dissociation behavior of humic and fulvic acids. Reactive and Functional Polymers, 128, 24–28. https://doi.org/10.1016/j.reactfunctpolym.2018.04.017

Kosmulski, M. (2006). pH-dependent surface charging and points of zero charge. Journal of Colloid and Interface Science, 298(2), 730–741. https://doi.org/10.1016/j.jcis.2006.01.003

Napoleão, D. A. S., Izário Filho, H. J., Siqueira, A. F., Bredda, E. H., Aguiar, L. G., Rós, P. C. M., & Alcântara, M. A. K. (2022). Comparative Study of Data Analysis Techniques for Photo-Fenton Degradation of Landfill Leachate. Industrial & Engineering Chemistry Research, 61(5), 1985–1993. https://doi.org/10.1021/acs.iecr.1c04087

Salvadores, F., Alfano, O. M., & Ballari, M. M. (2020). Kinetic study of air treatment by photocatalytic paints under indoor radiation source: Influence of ambient conditions and photocatalyst content. Applied Catalysis B: Environmental, 268, 118694. https://doi.org/10.1016/j.apcatb.2020.118694

Samanamud, G. R. L., Loures, C. C. A., Souza, A. L., Salazar, R. F. S., Oliveira, I. S., Silva, M. B., & Izário Filho, H. J. (2012). Heterogeneous Photocatalytic Degradation of Dairy Wastewater Using Immobilized ZnO. ISRN Chemical Engineering, 2012, 1–8. https://doi.org/10.5402/2012/275371

Silva, T. F. C. V., Soares, P. A., Manenti, D. R., Fonseca, A., Saraiva, I., Boaventura, R. A. R., & Vilar, V. J. P. (2017). An innovative multistage treatment system for sanitary landfill leachate depuration: Studies at pilot-scale. Science of The Total Environment, 576, 99–117. https://doi.org/10.1016/j.scitotenv.2016.10.058

Sun, W., Meng, S., Zhang, S., Zheng, X., Ye, X., Fu, X., & Chen, S. (2018). Insight into the Transfer Mechanisms of Photogenerated Carriers for Heterojunction Photocatalysts with the Analogous Positions of Valence Band and Conduction Band: A Case Study of ZnO/TiO 2. The Journal of Physical Chemistry C, 122(27), 15409–15420. https://doi.org/10.1021/acs.jpcc.8b03753

Turkten, N., & Bekbolet, M. (2020). Photocatalytic performance of titanium dioxide and zinc oxide binary system on degradation of humic matter. Journal of Photochemistry and Photobiology A: Chemistry, 401, 112748. https://doi.org/10.1016/j.jphotochem.2020.112748

Vithanage, M., Wijesekara, H., & Mayakaduwa, S. S. (2017). Isolation, purification and analysis of dissolved organic carbon from Gohagoda uncontrolled open dumpsite leachate, Sri Lanka. Environmental Technology, 38(13–14), 1610–1618. https://doi.org/10.1080/09593330.2016.1235229

Wiszniowski, J., Robert, D., Surmacz-Gorska, J., Miksch, K., Malato, S., & Weber, J.-V. (2004). Solar photocatalytic degradation of humic acids as a model of organic compounds of landfill leachate in pilot-plant experiments: Influence of inorganic salts. Applied Catalysis B: Environmental, 53(2), 127–137. https://doi.org/10.1016/j.apcatb.2004.04.017

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Publicado

05/05/2022

Cómo citar

NOHARA, N. M. L.; IZÁRIO FILHO, H. J.; ALCÂNTARA, M. A. K. de; OLIVEIRA, G. C. K. de; VERNILLI JUNIOR, F.; NOHARA, E. L.; OLIVEIRA, K. A. de; OLIVEIRA, M. F. de. Mezclas binarias de ZnO/TiO2 para la catálisis solar heterogénea de carbono orgánico no purgable en lixiviados de rellenos sanitarios. Research, Society and Development, [S. l.], v. 11, n. 6, p. e48411624570, 2022. DOI: 10.33448/rsd-v11i6.24570. Disponível em: https://www.rsdjournal.org/index.php/rsd/article/view/24570. Acesso em: 26 may. 2024.

Número

Vol. 11 Núm. 6

Sección

Ingenierías

Licencia

Derechos de autor 2022 Nicoly Milhardo Lourenço Nohara; Helcio José Izário Filho; Marco Aurélio Kondracki de Alcântara; Gabriel Caracciolo Koenigkam de Oliveira; Fernando Vernilli Junior; Evandro Luís Nohara; Kleberson Aristogenio de Oliveira; Marcos Fernandes de Oliveira

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